Here is the way,
1)Right click the my computer and select manage>>computer management >>storage >>Disk Management
2)Right click any of the drive and select shrink volume to make the
some of the space of the selected drive to be unallocated or select
Extend volume to extend the size of the selected drive if there is
already unallocated space
3)you can now allocate the unallocated
space to a new drive by right clicking it , selecting New simple volume
and followed by assigning the drive letter
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